| Маркер записи | n 22 3 4500 |
| Контрольный номер | uchm17_to86_no12_ss1173_ad1 |
| Дата корректировки | 13:43:41 13 мая 2025 г. |
| Кодируемые данные | 180212s2017||||RU|||||||||||#||||# rus0| |
| Системный контрольный номер | RUMARS-uchm17_to86_no12_ss1173_ad1 |
| AR-MARS | |
| Служба первич. каталог. |
Научная библиотека Чувашского государственного университета МАРС BY-HM0026 |
| Код языка каталог. | rus |
| Код языка издания |
eng eng |
| Индекс УДК | 544.4 |
| Индекс ББК |
24.542 24.542 |
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Таблицы для массовых библиотек Таблицы для массовых библиотек |
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Ischenko, A. A. doctor of chemical sciences; professor z01710 070 |
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Transient structures and chemical reaction dynamics [Текст] A. A. Ischenko, P. M. Weber, R. J. Dwayne Miller |
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| Иллюстрации/ тип воспроизводства | 69 рис. |
| Библиография | Библиогр.: с. 1245-1253 (580 назв. ) |
| Аннотация | To study transition structures that are formed in real time during a chemical reaction process, it is necessary to use ultrafast methods to follow the structural dynamics of molecular systems. For many decades, optical methods have been used to study the electronic states and time course giving rise to structural intermediates of chemical reactions with an ever higher time resolution. Although in some cases optical methods show many details, ultimately the results of these observations give only indirect information about the structure of the chemical reaction intermediates. Experimental observation of the behaviour of matter in the space-time continuum on ultrashort time scale is the necessary first step to explain and, subsequently, to control the nonequilibrium processes and functionality of the systems under study, to trace the relationship between the elements of the triad 'Structure-Dynamics-Function' to fully understand material properties. The results of these studies provide the necessary new information for testing theoretical approaches to the description of nonequilibrium chemical dynamics of molecular systems. The study of the time sequence of ultrafast processes occurring during the evolution of intermediate structures in the course of chemical reactions requires the integration of information that can be obtained by using complementary diffraction and spectroscopic methods based on various physical phenomena. Integration of data from ultrafast diffraction and spectroscopy makes it possible to investigate timescales prior to the onset of dissipation in which the coherent dynamics of matter can be observed. The use of quantum chemical calculations has reached a level of sophistication that makes it possible to explain the results of these experimental studies, the features of nonadiabatic behaviour of intermediate structures, and transition states of chemical reactions of molecular systems. This review analyzes the achievements of this rapidly developing field of modern chemistry, femtochemistry, to observe the primary events directing chemistry. |
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Химия AR-MARS Химическая кинетика AR-MARS |
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| Ключевые слова |
динамика химических реакций переходные процессы переходные структуры фемтосекундная спектроскопия фемтохимия химическая динамика химические реакции |
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Weber, P. M. professor 070 z02710 Dwayne Miller, R. J. director 070 z03710 |
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Moscow Technological University Institute of Fine Chemical Technologies named after M. V. Lomonosov z01100 Вторичная ответственность Brown University Department of Chemistry z02700 Providence Вторичная ответственность Max Planck Institute for the Structure and Dynamics of Matter Hamburg Centre for Ultrafast Imaging z03700 Germany Вторичная ответственность University of Toronto Departments of Chemistry and Physics z03700 Canada Вторичная ответственность |
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| ISSN | 0042-1308 |
| Название источника | Успехи химии |
| Место и дата издания | 2017 |
| Прочая информация | Т. 86, № 12. - С. 1173-1253 |
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RU 42813093 20180212 RCR |
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RU 42813093 20180212 |
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RU AR-MARS 20180212 RCR |
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RU AR-MARS 20180212 |
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| Тип документа | b |
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code year to no ss ad |
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uchm 2017 86 12 1173 1 |
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| 244 |
